1.  Safety
2.
Objectives/Overview
3.
Procedures
4. Observations
5.
Equipment
6.

View Techniques
A. Calibration of Temperature Probe
B. Determination of Heat Capacity
C. Heats of Solutions
D. Temperature Extrapolation from Graph

7.

Waste Disposal/Clean-up

8. Calculations/Set-ups
9. Conclusions
10. Grading Scale
11.
Sample Report Forms
11.
Review Prelab Questions
12. Review Postlab Questions

Experiment 7
Enthalpy of Solution

POSTLAB QUESTIONS

SHOW SET-UP FOR ALL PROBLEMS

1. A student performs an experiment involving the neutralization of NH3(aq) with HCl(aq) using a coffee cup calorimeter having a heat capacity of 15.6 J/g °C. The student mixes 50.0 mL of 1.00 M HCl with 50.0 mL of 1.00 M NH3. The temperature of the reaction solution is found to increase 6.5°C. Assume that the heat capacities of the solutions are 4.184 J/g°C and that the densities of the solutions are 1.00 g/mL.

a) Determine the heat (J and kJ) evolved by the acid-base reaction.

b) Calculate the number of moles of HCl and the number of moles of NH3 used in the experiment.

c) Determine the molar heat of neutralization (kJ/mol) of NH3(aq) with HCl(aq). If the accepted value is -51.7 kJ/mol, determine the student's percent error.

2. Determine the heat capacity of a calorimeter if 75.15 kJ of heat causes the temperature of the calorimeter to rise from 21.04 °C to 28.54 °C.

3. A student observes that the temperature rises slowly during the first ten minutes of the experiment (before reaction begins). Explain why the temperature is rising during this time.

 
 
 
 
 

 

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