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Experiment
7 POSTLAB QUESTIONS SHOW SET-UP FOR ALL PROBLEMS 1. A student performs an experiment involving the neutralization of NH3(aq) with HCl(aq) using a coffee cup calorimeter having a heat capacity of 15.6 J/g °C. The student mixes 50.0 mL of 1.00 M HCl with 50.0 mL of 1.00 M NH3. The temperature of the reaction solution is found to increase 6.5°C. Assume that the heat capacities of the solutions are 4.184 J/g°C and that the densities of the solutions are 1.00 g/mL. a) Determine the heat (J and kJ) evolved by the acid-base reaction. b) Calculate the number of moles of HCl and the number of moles of NH3 used in the experiment. c) Determine the molar heat of neutralization (kJ/mol) of NH3(aq) with HCl(aq). If the accepted value is -51.7 kJ/mol, determine the student's percent error. 2. Determine the heat capacity of a calorimeter if 75.15 kJ of heat causes the temperature of the calorimeter to rise from 21.04 °C to 28.54 °C. 3. A student observes that the temperature rises slowly during the first ten minutes of the experiment (before reaction begins). Explain why the temperature is rising during this time. |
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